IRIDIUM CHLORO-1,5-CYCLOOCTADIENE
Chloro(1,5-cyclooctadiene)iridium(I) dimer
CAS: 12112-67-3
Molecular Formula: C16H24Cl2Ir2
IRIDIUM CHLORO-1,5-CYCLOOCTADIENE - Names and Identifiers
| Name | Chloro(1,5-cyclooctadiene)iridium(I) dimer |
| Synonyms | IRIDIUM CHLORO-1,5-CYCLOOCTADIENE IRIDIUM I CYCLOOCTADIENE CHLORIDE Chloro-1,5-cyclooctadiene iridium(I) dimer Chloro(1,5-cyclooctadiene)iridium(I) dimer CHLORO(1,5-CYCLOOCTADIENE)IRIDIUM(I) DIMER CHLORO(1,5-CYCLOOCTADIENE)IRIDATE (I) DIMER BIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) DICHLORIDE IRIDIUM(I) CHLORIDE 1,5-CYCLOOCTADIENE COMPLEX DIMER DI-MU-CHLOROBIS[(ETA-CYCLOOCTA-1,5-DIENE)IRIDIUM (I)] 1,5-cyclooctadiene, chloride, (1Z,5Z)-, diiridium salt DI-MU-CHLORO-BIS[(1,2,5,6-ETA)-1,5-CYCLOOCTADIENE]DIIRIDIUM |
| CAS | 12112-67-3 |
| EINECS | 235-170-7 |
| InChI | InChI=1/2C8H12.2ClH.2Ir/c2*1-2-4-6-8-7-5-3-1;;;;/h2*1-2,7-8H,3-6H2;2*1H;;/p-2/b2*2-1-,8-7-;;; |
| InChIKey | XHOSESNLNGITPM-XRGHXPOKSA-L |
IRIDIUM CHLORO-1,5-CYCLOOCTADIENE - Physico-chemical Properties
| Molecular Formula | C16H24Cl2Ir2 |
| Molar Mass | 671.7 |
| Melting Point | 205°C (dec.)(lit.) |
| Boling Point | 153.5°C at 760 mmHg |
| Flash Point | 31.7°C |
| Water Solubility | insoluble |
| Vapor Presure | 4.25mmHg at 25°C |
| Appearance | Red-orange powder |
| Color | red to orange |
| Storage Condition | Keep in dark place,Inert atmosphere,2-8°C |
| Sensitive | 7: reacts slowly with moisture/water |
| MDL | MFCD00012414 |
IRIDIUM CHLORO-1,5-CYCLOOCTADIENE - Risk and Safety
| Hazard Symbols | Xi - Irritant |
| Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin. |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37/39 - Wear suitable gloves and eye/face protection |
| WGK Germany | 3 |
| FLUKA BRAND F CODES | 10 |
| TSCA | No |
| HS Code | 28439000 |
IRIDIUM CHLORO-1,5-CYCLOOCTADIENE - Introduction
A metal precursor for asymmetric allylic substitutions.
Last Update：2022-10-16 17:12:45
IRIDIUM CHLORO-1,5-CYCLOOCTADIENE - Reference Information
| Use | 1,5-cyclooctadiene iridium chloride dimer is iridium catalyzed by iridium for the asymmetric hydrogenation of unfunctionalized extracyclic double carbon bonds catalyst. In addition, it is also used to test new opox ligands from serine or threonine. 1, 5-cyclooctadiene iridium chloride dimer is an organic precious metal catalyst, used for the asymmetric hydrogenation reaction of non-functionalized outer ring double carbon bonds catalyzed by iridium. At the same time, it is also used to test new Neo phosphorus ligands, which are derived from serine or threonine. |
Last Update：2024-04-10 22:29:15
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View History
IRIDIUM CHLORO-1,5-CYCLOOCTADIENE
(S)-2-PiperazineMethanol dihydrochloride
8-羟基-5-亚硝基喹啉
METHYL 4-AMINO-3-FLUOROBENZENECARBOXYLATE
鞋用胶粘剂
619-03-4
3-Amino-3-(thiazol-5-yl)propan-1-ol dihydrochloride
(3R,5R)-7-(2-(4-FLUOROPHENYL)-5-ISOPROPYL-3-PHENYL-4-(PHENYLCARBAMOYL)-1H-PYRROL-1-YL)-3,5-DIHYDROXYHEPTANOIC ACID CALCIUM
(E)-4-(4-BROMOPHENYL)-4-OXOBUT-2-ENOIC ACID
2-Hydroxy-3,6-dimethyl-4-oxo-2-cyclohexene-1-carboxylic acid methyl ester
(S)-2-PiperazineMethanol dihydrochloride
8-羟基-5-亚硝基喹啉
METHYL 4-AMINO-3-FLUOROBENZENECARBOXYLATE
鞋用胶粘剂
619-03-4
3-Amino-3-(thiazol-5-yl)propan-1-ol dihydrochloride
(3R,5R)-7-(2-(4-FLUOROPHENYL)-5-ISOPROPYL-3-PHENYL-4-(PHENYLCARBAMOYL)-1H-PYRROL-1-YL)-3,5-DIHYDROXYHEPTANOIC ACID CALCIUM
(E)-4-(4-BROMOPHENYL)-4-OXOBUT-2-ENOIC ACID
2-Hydroxy-3,6-dimethyl-4-oxo-2-cyclohexene-1-carboxylic acid methyl ester